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|
| Type |
Symposium |
| Area |
[SRC Symposium] Biomimetic Catalysis Based on Porous Platform (BCP2) |
| Room No. |
Room 214 |
| Time |
WED 15:45-: |
| Code |
KCS4-7 |
| Subject |
Replaceable Lewis Acid Catalysts in Surface-modified Metal-Organic Frameworks |
| Authors |
Hakyung Yun, Jaheon Kim*
Department of Chemistry, Soongsil University, Korea
|
| Abstract |
A small-mesoporous metal-organic framework (MOF), Cr-MIL-101 has been chemically modified with polar functional groups such as amino acids, -NH2, or -COOH, and employed as a host for metal complex guests. To this MOF, pyridines having pendant alcohol groups such as pyridine propanol have been introduced via their H-bonding formation with the framework surfaces and used as new coordinating sites for metal ions that can show Lewis acid catalysis. Since various pyridine alcohols can attach to the framework surface, the platform host is useful for screening potential catalysts for organic reactions in an efficient way. In this presentation, we will explain in detail the synthesis, characterization, and applications of the platform MOF. |
| E-mail |
ganada51@naver.com |
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120th General Meeting of the KCS