121st General Meeting of the KCS

Type Poster Presentation
Area Organic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code ORGN.P-327
Subject Coordination-driven self-assembly of 3D supramolecular cages using triazole-based tetratopic donor
Authors JATINDER SINGH, DONGHWAN KIM, Kiwhan Chi*
Department of Chemistry, University of Ulsan, Korea
Abstract In recent years, coordination-driven self-assembly has become a dominant means of constructing functionalized metallosupramolecular architectures with promising applications such as molecular recognition, separation, catalysis and encapsulation of various guests. Coordination-driven self-assembled 3D supramolecular cages have attracted particular attention owing to their numerous potential applications such as containers for labile chemical species, molecular flasks for chemical reactions and transport vehicles for drug molecules. Our recent self-assembled prismatic cage was capable for sequential encapsulation of multiple aromatic guests in its large cavity.H1 Herein, we report the coordination-driven self-assembly of triazole-based tetratopic donor with various arene ruthenium acceptors. All the new metallosupramolecules have been characterized by elemental analysis, H1H NMR, H13C NMR and mass spectrometry.
E-mail jatinder.iitd@gmail.com