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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-32 |
| Subject |
Hydrogen bond scheme and domain structures in inorganic-organic layered hybrid perovskite type (C6H5CH2CH2NH3)2MnCl4 |
| Authors |
Garam Park, In-Hwan Oh1,*, J. M. Sungil Park1, Chang Seop Hong
Department of Chemistry, Korea University, Korea
1Korea Atomic Energy Research Institute, Korea
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| Abstract |
The layered perovskite compounds (C6H5CH2CH2NH3)2MeCl4 (Me = Cu2+, Mn2+, Fe2+) show a various crystal structures due to the combination of N-H…Cl hydrogen bonds and the motion of C6H5-CH2-CH2-NH3 organic molecules [1, 2, 3]. To understand the relationship between magnetic behaviors and the crystal structures and also to deliver the exact hydrogen bond scheme, we have investigated the crystal structures not only by X-ray single crystal diffraction method but also by neutron single crystal diffraction technique. In this study, we will show a crystal structure of (C6H5CH2CH2NH3)2MnCl4 obtained from neutron diffraction and compare this result with (C6H5CH2CH2NH3)2CuCl4 and also discuss the domain structures [4].
Reference
[1] A. O. Polyakov et al., Chem. Mater., 24 (2012) 133.
[2] S. H. Park et al., Dalton Trans., 41 (2012) 1237.
[3] Y. Nakayama et al., Angew. Chem. Int. Ed. 56 (2017) 1.
[4] G. Park et al., (2018) in preparation.
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| E-mail |
twg07@nate.com |
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121st General Meeting of the KCS