121st General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code INOR.P-42
Subject Synthesis and Structural Characterization of Cobalt(II), Cadmium(II) and Copper(II) Complexes Containing N,N’,X-Iminomethylpyridines
Authors Jaegyeong Lee, Hyosun Lee*
Department of Chemistry, Kyungpook National University, Korea
Abstract We have synthesized new series of 5-coordinate cobalt(II), cadmium(II) and copper(II) complexes by the reaction of [CoCl2•6H2O], [CdBr2•4H2O] and [CuCl2•2H2O] with N,N’,X-tridentate ligand (E)-2-morpholino-N-((pyridin-2-yl)methylene)ethanamine (Lmpme), respectively. Molecular structures of these complexes were characterized by single crystal X-ray diffraction. The catalytic properties of these complexes toward the polymerization of methyl methacrylate (MMA) in the presence of modified methylaluminoxane (MMAO) were investigated and compared to the reference metal starting materials.
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