|
|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-43 |
| Subject |
Synthesis and structural characterization of Zinc(II) and Cadmium(II) Complexes Containing 4-methoxy-N-(pyridin-2-yl)methylene)aniline Derivatives |
| Authors |
Hyungwoo Cho, Hyosun Lee*
Department of Chemistry, Kyungpook National University, Korea
|
| Abstract |
We have synthesized new series of new zinc(II) and cadmium(II) complexes with ligands Ln (Ln = LA - LC) where LA = 4-methoxy-N-(pyridin-2-ylmethylene)aniline, LB = 4-methoxy-N-(pyridin-2-ylmethyl)aniline, LC = 4-methoxy-N-methyl-N-(pyridin-2-ylmethyl)aniline. Molecular structures of [LAZnCl2] and [LBCdBr2] exhibited monomeric 4-coordinate tetrahedral geometry around metal center. However, [(LB)2ZnCl2] and [(LB)2CdBr2] showed 6-coordinate octahedral geometry around zinc and cadmium metal center through two equivalents of N,N’-bidentate ligands and two chlorides, respectively. Moreover, molecular structure of [LCZn(μ-Cl)Cl2]2 and [LCCd(μ-Br)Br]2 exhibited typical dimeric 5-coordinate trigonal bipyramidal geometry around metal center. |
| E-mail |
hyungwoo4@naver.com |
|
121st General Meeting of the KCS