121st General Meeting of the KCS

Type Poster Presentation
Area Organic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code ORGN.P-337
Subject Palladium-Catalyzed Asymmetric N-Regioselective Coupling Reaction of Indoles with Alkoxyallenes
Authors Seok Hyeon Jang, Hyun Woo Kim1, Young Ho RHEE*
Department of Chemistry, Pohang University of Science and Technology, Korea
1Chemical Simulation Center, Korea Research Institute of Chemical Technology, Korea
Abstract A new palladium-catalyzed asymmetric coupling reaction of indoles with alkoxyallenes is reported. Notably, the reaction showed complete regioselectivity for nitrogen regardless of electronic properties of indoles. This synthetic method offers highly efficient and flexible synthesis of N-glycosydic indoles.
E-mail jangsh@postech.ac.kr