121st General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code INOR.P-64
Subject Host-guest Conversion through in situ Crystallization in Photo-reaction
Authors Haeri Lee, Ok-Sang Jung*
Department of Chemistry, Pusan National University, Korea
Abstract Self-assembly of ZnBr2 with a bidentate ligand (L) yields 1D zigzag-chains, [ZnBr2L]∙(Solvate). The 1D chains form an ensemble constituting a unique supra-channel. The main driving forces for supra-channel ensembles are C-H∙∙∙π and π∙∙∙π interactions. Within the voids, solvate molecules exist depending on the anions and solvent system. [ZnBr2L]∙(Solvate) was recrystallized under UV-irradiation forming new 1D supra-channel structure. Further experiments and pervasive applications are in progress, the results of which certainly will yield more detailed information.
E-mail haeril@pusan.ac.kr