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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-66 |
| Subject |
Synthesis and Catalytic Properties of Bis-ligated Zinc(II) Coordination Complexes Containing Chiral Bidentate Ligand |
| Authors |
Kanagaraj Naveen, Ok-Sang Jung*
Department of Chemistry, Pusan National University, Korea
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| Abstract |
Construction of zinc(II) complexes by self-assembly of ZnX2 with (S)-(1-isonicotinoylpyrrolidin-2-yl)methyl isonicotinate (L) as a new chiral bidentate N-donor ligand produces a discrete metallacyclodimeric unit of [ZnX2 (L)] 2 complexes. The coordinating environment around zinc(II) complexes is typical tetrahedral and characterized by single crystal X-ray analysis. Furthermore, zinc(II) complexes have shown the effective catalyst for the transesterification reactions.
References
[1] H. Kim, M. Park, H. Lee and O.-S. Jung, Dalton Trans., 2015, 44, 8198.
[2] H. Lee, T. H. Noh and O.-S. Jung, Dalton Trans., 2014, 43, 3842.
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| E-mail |
kanagarajnaveen1990@gmail.com |
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121st General Meeting of the KCS