|
|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-69 |
| Subject |
Cu(I) Coordination Polymers Based on Podand Ligand with S Donor Atom |
| Authors |
Juhyeon Park, Jineun Kim, Hansu Im, Tae Ho Kim*, Myong Yong Choi*
Department of Chemistry, Gyeongsang National University, Korea
|
| Abstract |
Podand type dithioether ligand (L) was prepared by the reaction of 1,2-bis(2-chloroethoxy)ethane and benzylmercaptan. Coordination polymer {[Cu4I4L]·H2O}n (1) was synthesized by the reaction of H2O, L and CuI. CP 1 showed a 2D network structure based on cubane Cu4I4 cluster nodes. Luminescence spectra of previously reported [Cu4I4L]n (CP 2) exhibited an emission peak at about 565nm at room temperature. The results of our investigation including syntheses, structural characterization, thermal properties of CP 1 are presented. |
| E-mail |
jhpark_@gnu.ac.kr |
|
121st General Meeting of the KCS