121st General Meeting of the KCS

Type Poster Presentation
Area Organic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code ORGN.P-341
Subject Synthesis of New Light-Emitting Donor-Acceptor Material Based on Phenyl Phenothiazine and Phenyl Substituted Quinoline
Authors So Dam Kim, Tae Woo Kwon*
Department of Chemistry, Kyungsung University, Korea
Abstract New donor-acceptor molecule that included phenyl phenothiazine as the electron donor and phenyl substituted quinoline as the electron acceptor has been synthesized. Phenyl phenothiazine has been used as electron donor component due to their low reversible oxidation potentials by virtue of the sulfur atom which can facilitate the hole transport of the carrier. Phenyl substituted quinolines are well known to be a good electron acceptor materials. In this study, we report the synthesis of (E)-1,2-bis(4-phenyl-2-(10-phenyl-10H-phenothiazin-2-yl)-3-(p-tolyl)quinolin-6-yl)ethene via Ullmann, Grignard, Friedlander, Stille coupling reactions. Product was determined by using 1H, 13C NMR, MS, UV-Vis and Photoluminescence. Detailed synthetic routes and characterization will be described.
E-mail sdkim92@ks.ac.kr