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|
| Type |
Poster Presentation |
| Area |
Organic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
ORGN.P-346 |
| Subject |
Chemoselective Synthesis of Highly Functionalized N-Heterocyclic Glycosides by Ruthenium Catalyzed Olefin Isomerization |
| Authors |
Kyeongdeok Seo, Ye Ji Kim, Young Ho RHEE*
Department of Chemistry, Pohang University of Science and Technology, Korea
|
| Abstract |
Highly functionalized N-heterocyclic glycosides are particularly attractive due to their biological activities. Herein, we wish to report chemoselective synthesis of highly functionalized N-heterocyclic glycosides by ruthenium catalyzed olefin isomerization of cyclic allylic N-glycosides. Various N-heterocyclic glycosides were prepared with conservation of the chiral information of the labile N,O-acetal bond. The synthetic utility was demonstrated by preparation of various deoxyribonucleosides. |
| E-mail |
leosite@postech.ac.kr |
|
121st General Meeting of the KCS