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|
| Type |
Poster Presentation |
| Area |
Physical Chemistry |
| Room No. |
Event Hall |
| Time |
4월 20일 (금요일) 11:00~12:30 |
| Code |
PHYS.P-95 |
| Subject |
Reaction of Phthalazine driven by Gap Plasmons |
| Authors |
Sangwon Park, Kang Sup Lee1, Gyu Jin Yeon1, Zee Hwan Kim1,*
Department of Biophysics and Chemical Biology, Seoul National University, Korea
1Department of Chemistry, Seoul National University, Korea
|
| Abstract |
Plasmonic nanogap of Ag nanoparticle (AgNP, diameter: 80 nm) – phthalazine – Au thin film (AuTF, thickness: 10 nm) was illuminated with a light with λex = 632.8 nm and the evolution of the surface-enhanced Raman spectrum (SERS) is monitored. Appearance of new peaks of 489 cm-1 and 754 cm-1 were observed and were attributed to the photoproduct. Based on density-functional theory (DFT) simulation, we identify that the photoproduct is the dimers of the phthalazine, generated by the plasmonic hot-electron transfer from metallic surfaces to phthalazine. |
| E-mail |
sangwon91@snu.ac.kr |
|
121st General Meeting of the KCS