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|
| Type |
Poster Presentation |
| Area |
Organic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
ORGN.P-349 |
| Subject |
Synthesis of 4-hydroxybenzoic esters - Oxidation of substituted Hagemann's ester |
| Authors |
Dahye Kim, Sangho KOO1,*
Department of Energy Science and Technology, Myungji University, Korea
1Department of Chemistry, Myungji University, Korea
|
| Abstract |
In an effort to synthesize carotenoids with improved biological activity, we need to develop a practical synthetic method of diversely R-substituted 4-hydroxybenzoic esters as the terminal ring structure.
A practical two-step synthetic method of diversely R-substituted 4-hydroxybenzoic esters, which may have wide applications in household chemicals and polymeric materials, was developed by 2:1 coupling between ethyl acetoacetate and aldehydes (RCHO) in t-BuOK/t-BuOH, followed by oxidative aromatization of the resulting Hagemman’s esters by using stoichiometric NBS and catalytic TMS.OTf. |
| E-mail |
o_o4280@naver.com |
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121st General Meeting of the KCS