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| Type |
Poster Presentation |
| Area |
Organic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
ORGN.P-354 |
| Subject |
Research of synthetic method of Unnatural carotenoid |
| Authors |
Bo-ram Lim, Sangho KOO1,*
Department of Energy Science and Technology, Myungji University, Korea
1Department of Chemistry, Myungji University, Korea
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| Abstract |
Phenyl substituent is orthogonal to conjugated polyene chain, which can not conjugate with the chain. It is postulated that two phenyl substituents can be coordinated with metal ions when the proper distance is provided.
In order to synthesis of unnatural carotenoids, it is necessary to construct efficient building blocks for synthesis of unnatural carotene compound. Allylic sulfone unit containing phenyl substituents can be readily prepared from acetophenone derivatives via indium mediated addition and oxonia-cope rearrangement. Allylic aldehyde unit can be easily obtained. Based on our design, it is feasible to synthesize the conjugated polyene chain with di-phenyl substituents.
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| E-mail |
mickymart1@hanmail.net |
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121st General Meeting of the KCS