121st General Meeting of the KCS

Type Poster Presentation
Area Organic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code ORGN.P-357
Subject Regioselective C-H Alkenylation of Imidazoles
Authors YEJI HWANG, Jung Min Joo*
Department of Chemistry, Pusan National University, Korea
Abstract Pd-catalyzed regioselective C5-alkenylation of imidazoles has been developed using oxygen as an oxidant. This result was applied to Benzannulation of imidazoles using a sequence involving transposition of N-alkyl groups to give the C4-alkenylated imidazoles, alkenylation, thermal 6π-cyclization, and oxidation, affording unsymmetrically substituted benzimidazoles.
E-mail wotjd416@naver.com