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|
| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Event Hall |
| Time |
4월 20일 (금요일) 11:00~12:30 |
| Code |
MAT.P-365 |
| Subject |
Synthesis of new heteroleptic Ru(II) complexes and their application for dye-sensitized solar cells
|
| Authors |
jin hyung seo, yong rack choi1, Jungae Tak2, BYEONG HYO KIM*
Department of Chemistry, Kwangwoon University, Korea
1ST Pharm, Korea
2Department of Chemistry, Hanyang University, Korea
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| Abstract |
Among many green energies, research on dye-sensitized solar cells (DSSCs) using solar energy attracts attention. Recent researches have been engaged in the ligand design aiming to improve the photocurrent with a red-shift of the metal-to-ligand charge transfer (MLCT). To increase the absorption in the more red-shifted region, heteroleptic ruthenium(II) complexes were developed with various ancillary ligands in our group. As continuous study based on this idea, we designed new heteroleptic ruthenium(II) complexes by extending the π-conjugation of the anchoring ligand expecting better light harvesting ability. Consequently, we have synthesized new heteroleptic ruthenium(II) complexes with ancillary ligand (4,4`-bis(2-[1,1`-biphenyl]-4-yletheny])-2,2`-bipyridine) and anchoring ligands (different ɑ-diimine ligands). Dye-sensitized solar cells based on some of new ruthenium(II) complexes show noble power conversion efficiencies, which are comparable with that of the standard cell based on N719 |
| E-mail |
sjajh36@naver.com |
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121st General Meeting of the KCS