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| Type |
Poster Presentation |
| Area |
Analytical Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
ANAL.P-229 |
| Subject |
Self-Assemblies Based on Gold Nanoparticles with Bridge Molecules |
| Authors |
MINJUNG SEO, JI WON HA*
Department of Chemistry, University of Ulsan, Korea
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| Abstract |
Cucurbit[n]urils(CB[n]) are promising supramolecular hosts composed of glycoluril repeat units bridged by methylene group. Compared with other similar molecules, CB[n]s have unique properties that have rigid, highly symmetric and macrocyclic pumpkin-shaped structures. Its hollow cyclic structure can allow itself to contain other target molecules inside their hydrophobic cavities. Also, it can form strong host-guest interactions with identical carbonyl portals leading to generate uniform, stable sub-nanometer gaps of 0.9nm between gold nanoparticles that makes the powerful hot-spots capable of applications such as Surface-Enhanced Raman Scattering (SERS). In this study, we tried to make stable aggregations with gold nanoparticles using CB[n] as bridge molecules for regular alignments and confirm their structures and properties with analytical instruments such as electron microscopy, UV-vis, Raman spectroscopy.
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| E-mail |
minjung7760@naver.com |
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121st General Meeting of the KCS