121st General Meeting of the KCS

Type Poster Presentation
Area Organic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code ORGN.P-372
Subject Visible-light photoredox catalyzed Allylation of α-bromo carbonyl compounds using allylsilanes
Authors GwangSeok Jang, Sang Kook Woo1,*
Chemistry, University of Ulsan, Korea
1Department of Chemistry, University of Ulsan, Korea
Abstract

γ,δ-Unsaturated carbonyl compounds are well known as products of Clasien rearrangement reaction. These compounds allow further possible transformations due to the presence of a double bond. Therefore, many methods have been developed for their synthesis. The photochemical reactions of organic compounds provide a concise way to form complex molecular skeletons. Herein, we report highly regioselective synthetic method for γ,δ-unsaturated carbonyl compunds using visible light photoredox catalysis (Figure 1).

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