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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-81 |
| Subject |
C-H arylation of oxidated palladium nanoparticles using diaryliodonium oxidant |
| Authors |
MINJUN KIM, Hyunjoon Song*
Department of Chemistry, Korea Advanced Institute of Science and Technology, Korea
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| Abstract |
In organic chemistry, Direct C-H functionalization that converts C-H bond to reactive C-X bond has studied actively. In homogeneous catalysis, many studies about C-H functionalization have proceeded. However, heterogeneous catalysis, there are much fewer studies about C-H functionalization than homogeneous catalysis because of neutral metal state (0) of metal nanoparticles. Recent year, Glorius and co-workers reported that selective C-H direct arylation using diaryliodonium salts and proposed mechanistic studies proceeding via a Pd(o)/Pd(II) systems. But they didn’t confirm mechanism of C-H arylation. In this presentation, we report surface activation of palladium nanoparticles via diaryliodonium oxidants and mechanistic studies of direct C-H arylation of heterocyclic compounds using various analysis tools such as XPS, XAFS, TEM, etc. |
| E-mail |
minjun108@kaist.ac.kr |
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121st General Meeting of the KCS