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|
| Type |
Poster Presentation |
| Area |
Organic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
ORGN.P-392 |
| Subject |
Transition-metal-free synthesis of aromatic amines via the reaction of benzynes with isocyanates |
| Authors |
Dong wook Hwang, Haye Min Ko*
Department of Bio-nanochemistry, Wonkwang University, Korea
|
| Abstract |
An unexpected reaction between benzynes and isocyanates to generate aromatic amines has been developed under transition-metal-free conditions. The in situ prepared anions formed through cleavage of the N-C bond in isocyanates, reacted with aryne precursors to afford various aniline derivatives in moderate to excellent yield and tolerated various substituents on the o-silyl aryl triflate and the isocyanate. |
| E-mail |
hdw6926@naver.com |
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121st General Meeting of the KCS