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|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-120 |
| Subject |
A Titanium-Carboxylate Metal-Organic Framework Based on a Ti-oxo Chain Cluster |
| Authors |
Yesub Koum, Jinhee Park*
Department of Emerging Materials Science, Daegu Gyeongbuk Institute of Science & Technology, Korea
|
| Abstract |
Development of new titanium-based metal-organic frameworks (MOFs) with high crystallinity has been attracting significant research attention because it allows understanding of the structure-property relationship in their photocatalytic applications. Herein, we present a new single crystalline titanium-carboxylate MOF (1), which is built up from a porphyrinic linker and Ti-oxo chain cluster. 1 exhibits strong absorption in the visible light region. The photocatalytic activity of 1 was investigated by measuring the efficiency of singlet oxygen (1O2) generation upon the visible light (400-800 nm) irradiation. 1 showed the most efficient generation of 1O2 over Ti-oxo clusters, TiO2, and PCN-222. |
| E-mail |
yesub0177@dgist.ac.kr |
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121st General Meeting of the KCS