121st General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code INOR.P-124
Subject Metastable template (copper sulfide/phosphide) based synthesis of palladium copper sulfide/phosphide nanoparticles toward hydrogen evolution
Authors Haneul Jin, Jongsik Park, Kwangyeol Lee*
Department of Chemistry, Korea University, Korea
Abstract Finding materials with optimal surface energy for hydrogen attaching and detaching is of great interest to develop great catalysts toward hydrogen evolution. Pd is well known for its high H-binding affinity. However, it is too high to leave hydrogen gas easily as a product. Metastable materials such as CuxS and CuxP are great templates because of leachable characteristics of Cu to tune surface energy by leaving morphological and elemental features in the product. Herein, we synthesized PdαCuβS and PdγCuδP nanoparticles using CuxS and CuxP nanoplates as templates, respectively. As-synthesized nanoparticles showed great catalytic performances to hydrogen evolution reaction.
E-mail wls1945@korea.ac.kr