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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-135 |
| Subject |
Study on the crystal structures and properties of two copper(I) coordination polymers with polypyridine ligand |
| Authors |
Ahrim Jeong, Kil Sik Min1,*
Department of Chemistry, Kyungpook National University, Korea
1Department of Chemistry Education, Kyungpook National University, Korea
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| Abstract |
Recently, coordination polymers have received much attention because of their various structures and potential applications such as catalysis, magnetism, gas/solvent storage, separation, and photoluminescence. Two new copper(I) coordination polymer, [(tpmd)Cu2I2]n (1) (tpmd = N,N,N´,N´-tetra-4-pyridyl-methylenediamine) and [(dpab)Cu2I2]n•CH3OH (2) (dpab = bis-1,4,-(di-4-pyridylaminomethyl)benzene) have been prepared by the reaction of tpmd/dpab ligand and CuI. Compounds 1 and 2 have been characterized by infrared spectroscopy, elemental analysis, X-ray structural analysis, and photoluminescence. In complexes 1 and 2, each copper(I) ion has a distorted tetrahedral geometry with two nitrogen atoms of the coordinated ligand and two iodide anions. Compounds 1 and 2 were formed 2D polymers and extended to 3D structures due to the hydrogen bonding between the coordinated ligand and iodide anions. In this poster, we will present the detailed preparation, crystal structure, and properties. |
| E-mail |
ahrim24@gmail.com |
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121st General Meeting of the KCS