121st General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code INOR.P-136
Subject Synthesis of Palladium complexes containing diketonate and NHC ligands with bulky aryl groups and their catalytic activities towards functional norbornene polymerization
Authors DongJin Lee, Ik-Mo Lee*
Department of Chemistry, Inha University, Korea
Abstract Palladium complexes containing various NHC(N-heterocyclic carbene) ligands have been successfully synthesized by the reaction with diketonates. Treatments of Pd(acac)2 with NHC salt such as IPr·HCl, IMes·HCl resulted in [Pd(acac)(NHC)Cl] complexes and these complexes are characterized by NMR and elemental anaylsis. Moreover, these palladium complexes showed moderate to good catalytic activities towards functional norbornene polymerization.
E-mail ldj0321@hanmail.net