|
Type |
Poster Presentation |
Area |
Physical Chemistry |
Room No. |
Event Hall |
Time |
4월 20일 (금요일) 11:00~12:30 |
Code |
PHYS.P-161 |
Subject |
Unimolecular photodissociation of chlorobenzene cations |
Authors |
HyunWook Choi, BongGyu Jeong, Seung Min Park* Department of Chemistry, Kyung Hee University, Korea |
Abstract |
Photodissociation decay times of chlorobenzene cations (Bz35Cl+, Bz37Cl+) have been investigated by linear tandem time-of-flight mass spectrometer. Mass-selected Bz35Cl+, Bz37Cl+ were irradiated by various photons (230 to 305 nm). Photodissociation rate constant of chlorobenzene cations depends on the internal energy and isotope effect. Ionization energy was calculated by Gaussian 09 program at the B3LYP / cc-pVTZ theory level of DFT method. |
E-mail |
xzxzxz21@naver.com |
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