121st General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code INOR.P-147
Subject Self-assembly of 1-D azamacrocyclic compound with significant CO2 capture
Authors Jong Won Shin*, Dae-Woong Kim1, Dohyun Moon1,*
Division of Daegu, Korea Institute of Science and Technology Informat, Korea
1Beam Operation Team, Pohang Accelerator Laboratory, Korea
Abstract Supramolecular compounds constructed from nickel(II) azamacrocyclic compound have been attracted much interest in the development of new functional materials owing to their potential applications in molecular sensing, adsorbents for carbon dioxide and metalloenzymes. To obtain stable 1-D nickel(II) azamacrocyclic compound, we prepared self-assembly of nickel(II) azamacrocyclic complex, containing butyl pendant groups, with 2,7-naphthalenedicarboxylic acid (2,7-NDC) as organic linker. The 2,7-naphthalenedicarboxylic acid (2,7-NDC) can easily bind or interact with transition metal ions as various coordination modes because 2,7-NDC can be fully or partially deprotonated and act as supramolecular interaction donors or acceptors as hydrogen bonding and π-π interaction. Here, we will present the detailed preparation of the [Ni(C16H38N6)(2,7-NDC)] compound, interestion crystal structures as well as gas adsorption.
E-mail jwshin@kisti.re.kr