121st General Meeting of the KCS

Type Poster Presentation
Area Organic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code ORGN.P-467
Subject Chirality sensing amino acids via stereodynamic Zn-complex self-assembly
Authors Qian Chen, kwan mook kim1,*
Department of Chemistry and Nano Science, Ewha Womans University, Korea
1Department of Chemistry, Ewha Womans University, Korea
Abstract Chirality plays an essential role in modern science and pharmaceutical. The development for analysis of chiral compound in a rapid, accurate, time-saving way has attracted huge interest. In this study, A DPA-Zn-complex was found to be an efficient stereodynamic chemosensor for simultaneous determination of absolute configuration and enantiomeric composition of amino acids via circular dichroism spectrum. A self-assembly of amino acids, Zn2+, and probe 1 produces characteristic CD signals between 308-310 nm at low concentrations. The quantitative sensing approach has a potential in high-throughput application.
E-mail chenqian2007@outlook.com