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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-174 |
| Subject |
The Aerobic Oxidation of Cyclohexene with Copper Silicate, SGU-29 |
| Authors |
Dong Hyeon Lee, Hyun Sung KIM1,*
Department of chemistry, Pukyong National University, Korea
1Department of Chemistry, Pukyong National University, Korea
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| Abstract |
Catalytic partial oxidation of allylic compound is one of the important routes in industrial chemistry. Nanoporous materials related to zeolites and zeotypes are widely employed as its heterogeneous catalysts or host materials of catalytic molecules in the field of partial oxidation research. Herein, we report the catalytic activity of SGU-29, which is a kind of zeoypes, containing square plane-oxygenated Cu (II) active site for aerobic oxidation of cyclohexene. A catalytic performance was achieved under The SGU-29 heterogeneous catalytic reaction performed under mild reaction conditions, 1 bar of O2 at 70℃. Under the reaction conditions investigated, the aerobic oxidation of cyclohexene mainly produced 2-cyclohexen-1-ol, 2-cyclohexen-1-one, cyclohexenyl hydroperoxide. And conversion efficiency of SGU-29 for cyclohexene oxidation reach 13% under 1 bar of O2 at 70℃ within 4h. |
| E-mail |
ldh1825@naver.com |
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121st General Meeting of the KCS