121st General Meeting of the KCS

Type Poster Presentation
Area Physical Chemistry
Room No. Event Hall
Time 4월 20일 (금요일) 11:00~12:30
Code PHYS.P-209
Subject Vibrational circular dichroism spectroscopy of jet-cooled chiral molecules
Authors Changseop Jeong, ARAM HONG, Nam Joon Kim*
Department of Chemistry, Chungbuk Natioanl University, Korea
Abstract Vibrational circular dichroism (VCD) spectroscopy is differential absorption between left-handed and right-handed circularly polarized light in IR region. We have developed VCD spectroscopy applicable to gas phase chiral molecules. Circular polarized IR laser pulses alternating left-handed and right-handed were generated using photoelastic modulator. Chiral molecules in a supersonic jet were irradiated with circularly polarized IR laser pulses and ionized with UV laser pulses by resonance-enhanced multi photon ionization (REMPI). We investigated that the enantiomeric pair of the chiral molecule shows opposite sign in OH stretch region with good S/N ratio.
E-mail spd2002@naver.com