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|
| Type |
Poster Presentation |
| Area |
Organic Chemistry |
| Room No. |
Event Hall |
| Time |
4월 19일 (목요일) 11:00~12:30 |
| Code |
ORGN.P-518 |
| Subject |
Photochromic Reaction of Merocyanine-sulfonate |
| Authors |
Goeun Choi, Eun Ju Shin*
Department of Chemistry, Suncheon National University, Korea
|
| Abstract |
Merocyanine-sulfonate photoacid have been reported over the past few years for controlling proton transfer in chemical, material and biological processes. Sulfonate-functionalized merocyanine photoacid (MEH) undergoes a cyclization reaction under visible light to form a protonated spiropyran (SPH), which is highly acidic. Sulfonate-functionalized merocyanine acts as a photoacid. On irradiation of visible light, it can reversibly change magnitude of proton concentration. Protonated spiropyran (SPH) releases a proton to form a spiropyran.
In this study, merocyanine-sulfonate type photoacid has been synthesized and its reversible photochromic reaction has been investigated by absorption and fluorescence spectroscopic methods. |
| E-mail |
ejs@sunchon.ac.kr |
|
121st General Meeting of the KCS