121st General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code INOR.P-190
Subject Synthesis and Photophysical Properties of Novel Host-Guest Systems Based on Salen-Al/Carbazole
Authors Sang Woo Kwak, Hyomin Jin1, Kang Mun Lee2, Yongseog Chung, Myung Hwan Park3,*
Department of Chemistry, Chungbuk Natioanl University, Korea
1Kangwon National University, Korea
2Department of Chemistry, Kangwon National University, Korea
3Department of Chemical Education, Chungbuk Natioanl University, Korea
Abstract A new type of luminescent carbazole-containing organometallic complexes has received much interest because it can exhibit interesting optical properties such as emission-color tuning and increase of quantum efficiency. We have recently developed salen-Al dyads containing other functional groups, such as boron dipyrromethane (BODIPY) and triarylborane (TAB), thus controlling intramolecular energy transfer (IET) between them as well as leading to unique emission features. In this regard, we designed novel host-guest systems based on the salen-Al complexes containing carbazole units to induce unique photophysical changes and enhance the emission efficiency. The detailed synthesis, characterization, and optical properties of these host-guest systems (D1 and D2) in conjunction with theoretical calculations will be described.
E-mail sangwoo814@hanmail.net