121st General Meeting of the KCS

Type Poster Presentation
Area Material Chemistry
Room No. Event Hall
Time 4월 20일 (금요일) 11:00~12:30
Code MAT.P-541
Subject Enhanced photoelectrochemical water oxidation using Mo:BiVO4/WO3
Authors Jae Ryeol Jeong, Min Hyung Lee*
Department of Applied Chemistry, Kyung Hee University, Korea
Abstract Cation doping and heterojunction formation in semi-conductors are often studied to improve efficiency and stability of photoelectrochemical (PEC) water splitting electrodes and catalysts. For example, Molybdenum doped BiVO4 can improve photo reaction currents, and ZnO/BiVO4 heterojunction can improve PEC performance. In this poster, we present sol-gel synthesized lithium and molybdenum co-doped BiVO4(Li-Mo:BiVO4) with WO3heterojunction (denoted as Li-Mo:BiVO4/WO3) that shows enhancement of PEC water oxidation, increasing current density from 1.0 to 2.8 mA/cm2 (at 1.6 V vs. RHE) and also decrease band-gap from 2.66 to 2.24 eV compared to pristine Mo:BiVO4.
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