121st General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Event Hall
Time 4월 19일 (목요일) 11:00~12:30
Code INOR.P-219
Subject Temperature and time dependent control of meso-porosity in metal-organic frameworks
Authors Seok Jeong, Myoung Soo Lah*
Department of Chemistry, Ulsan National Institute of Science and Technology, Korea
Abstract Non-interpenetrated three-dimensional metal-organic framework (MOF) with hms topology is converted to doubly interpenetrated analogues with hms-c topology by thermal treatment. Depending on thermal treatment condition and the property of the neutral pillaring linker, the defects of the MOFs can be potentially controlled. Combination of non-stoichiometric removal of neutral pillaring linkers from MOFs and partial collapse of two-dimensional sheets could lead to new hierarchically porous interpenetrated MOFs that contain both micro- and mesopores simultaneously.
E-mail jsbeat@unist.ac.kr