122nd General Meeting of the KCS

Type Oral Presentation
Area Oral Presentation for Young Polymer Scientists
Room No. Room 325C+D
Time THU 09:30-:
Code POLY.O-4
Subject Biodegradable Shape Memory Polymers: Amino Acid-Based Poly(Ester Urea)s for Biomedical Applications
Authors Gregory Peterson
Chemistry, Seoul National University, Korea
Abstract The thermal shape memory behavior of a series of amino acid-based poly(ester urea)s is explored. We demonstrate that these materials exhibit excellent shape memory performance in dual- and triple-shape thermomechanical testing over a range of amino acids and chain extender lengths. The mechanism of shape transformation and recovery is attributed to activation of chain mobility above the glass transition temperature as well as a strong hydrogen bonding network. Additionally, we demonstrate that we can tune the shape memory properties of these materials with polymer blending, enabling quadruple-shape memory cycles. The significance of these findings will be discussed in relation to other biodegradable shape memory polymers and to relevant biomedical applications.
E-mail gpeterson@snu.ac.kr