|
Type |
Poster Presentation |
Area |
Inorganic Chemistry |
Room No. |
Grand Ballroom |
Time |
10월 19일 (금요일) 11:00~12:30 |
Code |
INOR.P-28 |
Subject |
Reactions of dialkyl Pd(II) and Pt(II) complexes with organic tetrazole-thiones |
Authors |
Yong-Joo Kim*, Seung Hyun Kim1, Heekwon Park1, Soon W. Lee2 Department of Chemistry, Gangneung-Wonju National University, Korea 1Chemistry, Gangneung-Wonju National University, Korea 2Department of Chemistry, Sungkyunkwan University, Korea |
Abstract |
Various tetrazole-thiolato Pd(II) or Pt(II) complexes were obtained from the reactions of trans-PdEt2(PR3)2 or cis-PtEt2(PR3)2 with organic tetrazole-thiones {S=[C{HN4(R)}]. The isolated complexes were determined by IR and NMR spectroscopy and X-crystallographic analyses. Treatments of alkyl Pd(II) or Pt(II) tetrazole-thiolato complexes with another {S=[C{HN4(R)}] afforded coresponding new bis(tetrazole-thiolato) Pd or Pt(II) complexes. Experimental detail will be discussed. |
E-mail |
yjkim@kangnung.ac.kr |
|