122nd General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Grand Ballroom
Time 10월 19일 (금요일) 11:00~12:30
Code INOR.P-28
Subject Reactions of dialkyl Pd(II) and Pt(II) complexes with organic tetrazole-thiones
Authors Yong-Joo Kim*, Seung Hyun Kim1, Heekwon Park1, Soon W. Lee2
Department of Chemistry, Gangneung-Wonju National University, Korea
1Chemistry, Gangneung-Wonju National University, Korea
2Department of Chemistry, Sungkyunkwan University, Korea
Abstract Various tetrazole-thiolato Pd(II) or Pt(II) complexes were obtained from the reactions of trans-PdEt2(PR3)2 or cis-PtEt2(PR3)2 with organic tetrazole-thiones {S=[C{HN4(R)}]. The isolated complexes were determined by IR and NMR spectroscopy and X-crystallographic analyses. Treatments of alkyl Pd(II) or Pt(II) tetrazole-thiolato complexes with another {S=[C{HN4(R)}] afforded coresponding new bis(tetrazole-thiolato) Pd or Pt(II) complexes. Experimental detail will be discussed.
E-mail yjkim@kangnung.ac.kr