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|
| Type |
Poster Presentation |
| Area |
Physical Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 19일 (금요일) 11:00~12:30 |
| Code |
PHYS.P-190 |
| Subject |
Nucleophilic Substitution Reaction of Anthraquinone-2-Carbonyl Chloride |
| Authors |
Han joong Koh
General Science Education, Jeonju National University of Education, Korea |
| Abstract |
The nucleophilic substitution reaction of anthraquinone-2-carbonyl chloride (1) were studied kinetically in various mixed solvents. The analysis using the extended Grunwald-Winstein equation in the reaction of anthraquinone-2-carbonyl chloride obtained the l value of 2.11, the m value of 0.54, and the correlation coefficient of 0.955. The nucleophilic substitution reaction of 1 might proceed via an associative SN2 mechanism enhancing bond making than bond breaking in the transition state.. |
| E-mail |
hankoh@jnue.kr |
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122nd General Meeting of the KCS