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|
| Type |
Poster Presentation |
| Area |
Organic Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 18일 (목요일) 11:00~12:30 |
| Code |
ORGN.P-60 |
| Subject |
Design and synthesis of CNT-Chitosan-Ni and CNT-Chitosan-Pd nanohybrid catalytic platform and its application to the ipso-hydroxylation of arylboronic acids |
| Authors |
Minji Kim, Eunjae Shin1, Seongryu Joo2, Seung-Hoi Kim2,*
Dankook University, Korea
1Chemistry, Dankook University, Korea
2Department of Chemistry, Dankook University, Korea
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| Abstract |
we have developed an efficient, economical, and practical strategy for the synthesis of functionalized phenols via the ipso-hydroxylation of arylboronic acids using recyclable, reusable Pd- or Ni-catalyst platform under mild conditions. The developed method has the following advantages such as cost-effectiveness using a versatile oxidant (H2O2), and, more importantly, recyclability of the catalyst. Additionally, the easy workup procedure that yields pure products is highly beneficial. Overall, we believe that this approach is the first example of the use of a palladium- or nickel-catalyst in the ipso-hydroxylation of arylboronic acids. |
| E-mail |
sunglyu@gmail.com |
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122nd General Meeting of the KCS