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|
| Type |
Oral Presentation |
| Area |
Oral Presentations for Young Scholars in Organic Division |
| Room No. |
Room 325A+B |
| Time |
THU 09:30-: |
| Code |
ORGN.O-3 |
| Subject |
Pd(ll)-Catalyzed Regioselective Formation of 1-Hydroxycarbazoles |
| Authors |
Youngho Kim, So Won Youn*
Department of Chemistry, Hanyang University, Korea
|
| Abstract |
Recently, we developed a Pd-catalyzed regioselective cyclization reaction of N-Ts-2-amino-3'-hydroxylbiaryls under mild aerobic conditions to afford 1-hydroxycarbazoles. Dual directing group-assisted C–H activation at the sterically more hindered C2'-position of 2-amino-3'-hydroxylbiaryls appears to occur. Moreover, complicated natural products were successfully synthesized, demonstrating the synthetic utility of this method. |
| E-mail |
glossy3945@naver.com |
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122nd General Meeting of the KCS