122nd General Meeting of the KCS

Type Poster Presentation
Area Organic Chemistry
Room No. Grand Ballroom
Time 10월 18일 (목요일) 11:00~12:30
Code ORGN.P-71
Subject Unusual helical struture nylon-like oligomers containing cyclic dicarboxylic acid and diamine residues
Authors Sunglim Choi, Soo Hyuk Choi*
Department of Chemistry, Yonsei University, Korea
Abstract

In the previous study, we synthesized and studied various oligomers using cyclic β-amino acids such as amino cyclopentane carboxylic acid (ACPC) and amino cyclohexane carboxylic acid (ACHC). In particular, trans compounds form beta sheets, showing that they form 10/12 or 12/10 helix structures using cis compound. In this study, we tried to implement helical structures of nylon-like oligomers, which were synthesized using 1,2-diamine and 1,2-dicarboxylic acid. However, synthesized oligomers with acyclic residues were not robust, so cyclic residues were incorporated into oligomers, because we expected that helical propensity of the oligomers is enhanced. In addition, cyclic residues may increase the solubility in organic solvents. For the above reasons, the oligomers were synthesized using acetoneide and cylopentane diamine. And we analysized synthesized compounds through CD, IR, and 2D NMR.

E-mail sjloveses@yonsei.ac.kr