122nd General Meeting of the KCS

Type Poster Presentation
Area Inorganic Chemistry
Room No. Grand Ballroom
Time 10월 19일 (금요일) 11:00~12:30
Code INOR.P-55
Subject Synthesis of New Zeolitic Imidazolate Frameworks Using Functional Imidazoles and Structure Directing Agents
Authors Joohan Nam, Yeongjin Kim, Seunghee Han1, Yoojong Park1, Soochan Lee2, Wonyoung Choe3,*
School of Natural Science, Ulsan National Institute of Science and Technology, Korea
1School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology, Korea
2Department of Chemistry, Ulsan National Institute of Science and Technology, Korea
3Department of Chemistry, Ulsan National Institute of Science and Technology, United States
Abstract In recent years, porous materials are widely used as chemical catalyst, solar cell, sensor, and so on. Among them, zeolite is one of the most famous porous materials. Zeolite has been widely used for various applications because of its stability and sorption ability. Zeolitic Imidazolate Frameworks(ZIFs) are Zeolitic MOFs(ZMOFs) that mimic zeolite, which consist of tetrahedral transition metals (Zn, Co) and various imidazoles. ZIFs share structural advantages of zeolite. However, chemical properties of ZIFs can be more easily modulated unlike zeolites. Interestingly, the number of topologies in ZIFs is relatively small compared to that for zeolites. Therefore, we have synthesized new ZIFs with new topology. In this presentation, we show that both Organic Structure-Directing Agents(OSDAs) and functional groups in ZIFs play important roles to stabilize ZIF cages.
E-mail n1169jh@gmail.com