122nd General Meeting of the KCS

Type Poster Presentation
Area Organic Chemistry
Room No. Grand Ballroom
Time 10월 18일 (목요일) 11:00~12:30
Code ORGN.P-80
Subject Synthesis of a crown ether strapped calix[4]pyrrole and its ion pair recognition
Authors Nam Jung Heo, Sung Kuk Kim*
Department of Chemistry, Gyeongsang National University, Korea
Abstract A new ion pair receptor based on calix[4]pyrrole strapped with a bisazacrown ether was synthesized. This receptor consists of calix[4]pyrrole having two phenoxy walls and a diaza crown ether linking diagonal phenoxy groups. The ion pair receptor was found to be able to bind various ion pairs such as akali metal halide salts. In this case, the metal cation was complexed to the bisazacrown ether ring whereas the anions were bound to the calix[4]pyrrole. More details on ion pair binding properties of the ion pair receptor will be presented.
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