Carbon dioxide (CO₂) the major contributor to climate change becoming increasingly apparent and worrisome due to its role as greenhouse gas. Conversion of anthropogenic (CO₂) to value-added chemicals through solar driven catalysis considered as an appealing approach to tackle CO₂ emission challenges. Although materials developed to produce high energy fuels from CO₂ reduction with water, it is still a challenge to develop suitable, highly efficient and stable nanostructures for long time operation. As CO₂ reduction reaction requires participation of multiple electrons, only nano hybrids involving two are more selective co-catalysts is beneficial. Herein, we report photo deposited Pt on core shell structured CdS-ZnS nano hybrid as durable catalyst for CO₂ reduction. The unique design integrates covering of CdS nanorods with ZnS shells and further photo reduction of H₂PtCl₆ onto CdS/ZnS in water-alcohol system. This delicate design accelerates the separation and transfer of photo generated charges, enhanced the photo absorption, reduced photo corrosion of CdS and facilitates abundant catalytic active sites. The as-synthesized CdS/ZnS/Pt nano hybrids are investigated for photocatalytic CO₂ reduction with water to produce CO and CH₄ in presence of Tri ethanol amine (TEOA) as hole (h⁺) scavenger. The optimized CdS/ZnS/Pt catalyst exhibited good stability for more than 42 hrs with unbroken rate of reaction for CO generation. The hybrid material realizes efficient solar-to-chemical energy conversion in suspension, demonstrating the potential of delicate structured materials are highly efficient and stable catalysts for photo reduction of CO₂.