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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 19일 (금요일) 11:00~12:30 |
| Code |
INOR.P-66 |
| Subject |
Time-dependents self-assembly. Transformation of Cyclophane-Type 1D Linked Ring into Simple Linked Ring |
| Authors |
Dongwon Kim, Ok-Sang Jung*, SeongHyeon Park
Department of Chemistry, Pusan National University, Korea
|
| Abstract |
Self-assembly of AgX( X = CF3SO3- and PF6-) with 1,3,5-tris(nicotinoyloxy-methyl)benzene (L) initially produces a cyclophane-type 30-membered macrocyclic linked 1D network with composition of Ag(I) and L of 3:2 irrespective of anion and solvent. After 20 days, The 1D networks of [Ag9(CF3SO3)4L6(C4H8O)5](CF3SO3)5 and [Ag3L2(C4H8O)2](PF6)3 are changed the crystalline products in the mother liquor are changed to 16-membered macrocyclic linked 1D with composition of Ag(I) and L of 1:1 ratio into [AgL(CF3SO3)] and [AgL](PF6). All crystal structures show significantly the metallophilicity of two anions CF3SO3- and PF6-. |
| E-mail |
dwkim7459@pusan.ac.kr |
|
122nd General Meeting of the KCS