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|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 19일 (금요일) 11:00~12:30 |
| Code |
INOR.P-67 |
| Subject |
Cage Effect on Oxidation via Pd2L4 Prolate Spheroid |
| Authors |
EunSoo Yi, Ok-Sang Jung*, Hyejin Oh
Department of Chemistry, Pusan National University, Korea
|
| Abstract |
Self-assembly of PdX2 (X- = NO3-, BF4-, and CF3SO3-) with 2,6-bis(4′-nicotinamidephenoxy)naphthalene (L) forms a series of [Pd2L4]X4 prolate spheroids. The O donors of two Me2SO molecules within the prolate spheroid cage are oriented toward Pd(II) metal centers. In the presence of H2O2, the nestled Me2SO within cage is efficiently oxidized to Me2SO2 at room temperature. The cage effect will be discussed. |
| E-mail |
eunsoo@pusan.ac.kr |
|
122nd General Meeting of the KCS