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|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 19일 (금요일) 11:00~12:30 |
| Code |
INOR.P-68 |
| Subject |
Synthesis and Catalytic Effects of Bimetallic Copper(II) Cases |
| Authors |
Lingling Yang, Jyoti Ramesh Jadhav, Ok-Sang Jung*
Department of Chemistry, Pusan National University, Korea
|
| Abstract |
Self-assembly of Cu(OTf)2 with a new N,N',N''-((benzene-1,3,5-triyltris(oxy))tris(benzene-2,1-diyl))trinicotinamide ligand (L) in a mixed solution of acetone and chloroform gives rise to crystals of cyclodimeric [Cu2L2(OTf)3(acetone)(H2O)2]·3CHCl3·(OTf)·H2O. When the crystal was recrystallized in a mixture of tetrahydrofuran and chloroform, new blue crystal, [Cu2L2(OTf)3(H2O)3]·3CHCl3·THF·(OTf)·H2O, was obtained after 4 days. Their skeletal structrues are originally similar except for coordinated acetone and H2O molecules, respectively. These crystals have been employed as catalysts for 3,5-di-tert-butylcatechol oxidation, showing significant different catalytic effects between two species. |
| E-mail |
yll19901013@pusan.ac.kr |
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122nd General Meeting of the KCS