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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 19일 (금요일) 11:00~12:30 |
| Code |
INOR.P-69 |
| Subject |
Synthesis and Recognition of Cyclodimeric Zn(II) Complexes |
| Authors |
SooMin Hyun, Ah Reum Kim, Ok-Sang Jung*
Department of Chemistry, Pusan National University, Korea
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| Abstract |
Self-assembly of ZnI2 with di(isoquinolin-5-yl)isophthalate (L) as a new bidentate N-donor gives rise to a discrete crown-shaped M2L2 architecture, [Zn2I4L2]⋅4CH3CN⋅THF. These cyclodimers constitute, a characteristically eclipsed molecular array, resulting in the formation of channels. The metallocyclodimer effectively stabilizes/recognizes a combination aggregate of unstable CH2I2 and benzene molecules. UV-irradiation 254 nm on [Zn2I4L2]⋅4CH3CN⋅THF crystal has been attempted. Their photoreactivity will be presented.
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| E-mail |
gustnals8@pusan.ac.kr |
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122nd General Meeting of the KCS