In recent years, organic-inorganic hybrid perovskites such as methylammonium lead halides (MAPbI₃), which can increase the efficiency of solar cells, have been widely investigated owing to their low costs and simple processes of production. A new hybrid chiral material composed of (R)/(S)-1-phenylethylamine and bismuth bromide was synthesized using a mild solution chemistry method. Single crystal X-ray diffraction analysis indicates that both (R)- and (S)-configuration materials were successfully synthesized. To find applicability to photovoltaic or optoelectronic devices, the newly synthesized chiral materials were uniformly deposited on glass substrates by the spin-coating method. Powder X-ray diffraction analysis on the chiral thin films indicate that both (R)- and (S)-configuration materials reveal a strong preferred orientation along the crystallographic a-axis. We also determined the chirality of thin films through solid state circular dichroism analysis. Infrared spectra, UV-vis reflectance spectra, and second harmonic generation measurements were also performed for both polycrystalline as well as thin film samples.