|
|
| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 18일 (목요일) 11:00~12:30 |
| Code |
MAT.P-364 |
| Subject |
Facile Synthesis of Coordination Polymer Nanocubes and Post-Modification through Secondary Metal Ion Decoration |
| Authors |
Ngoc Minh Tran, Hien Duy Mai1, Hyojong Yoo1,*
Chemistry, Hallym University, Korea
1Department of Chemistry, Hallym University, Korea
|
| Abstract |
Coordination polymer particles (CPPs) are generally formed through the coordination-driven assembly of metal ions or clusters with multitopic organic linkers. Their high degree of porosity, well-defined pore size, and structural tailorability render them promising candidates for diverse applications. Herein, we report a shape-controllable synthetic protocol for Zinc-based coordination polymer nanocubes (Zn-CPNs). In the synthesis, 2,6-bis[(4-carboxyanilino)carbonyl] pyridine ([N3]) ligand is employed as an efficient shape-directing modulator to control the size and shape of Zn-CPNs. More importantly, the Zn-CPNs provide plenty of metal binding sites and beneficial defects in the structure, which is suitable for the coordination of other functional metal ions. The secondary metal ion-modified Zn-CPNs exhibit improved catalytic activities. |
| E-mail |
tranminhngoc.hueuni@gmail.com |
|
122nd General Meeting of the KCS