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|
| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 18일 (목요일) 11:00~12:30 |
| Code |
MAT.P-366 |
| Subject |
Metallocavitand-Induced Cage-like Crystal Packing within High-Order Cobalt Cluster-based Supramolecular Assemblies |
| Authors |
Philjae Kang, Hien Duy Mai, Hyojong Yoo*
Department of Chemistry, Hallym University, Korea
|
| Abstract |
A cobalt (Co) supramolecular triple-stranded helicate, [Co8(PDA)6(Br-PTA)3(DMF)4(H2O)2] (1) (PDA = 2,6-pyridinedicarboxylate, Br-PTA = 5-bromoisophthalate, DMF = dimethylformamide), is successfully synthesized and fully characterized. The solid-state structure of 1 shows that four cobalt atoms are coordinated by three PDA ligands to form a tetranuclear cobalt cluster with three extension points and the ditopic Br-PTA ligands interlink two basic assembly units. In crystal packing, the bromo group is surrounded by the cavity-like tetranuclear cobalt cluster, which acts as a metallocavitand, to generate a unique cage-like crystal packing geometry. The isomorphous molecular cage, which exhibits similar crystal-packing geometry as observed in 1, is also successfully isolated. This is an unusual example of a highly symmetric cage-like crystal packing architecture, resulting from the interaction among metallocavitands of in-situ generated supramolecular modules. |
| E-mail |
phil-wo@nate.com |
|
122nd General Meeting of the KCS