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|
| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 18일 (목요일) 11:00~12:30 |
| Code |
MAT.P-368 |
| Subject |
Synthesis of Metallosupramolecular Nanocages through the Assembly of Triple-Stranded Helicates. |
| Authors |
Hai Minh Van Ho, Hien Duy Mai1, Hyojong Yoo1,*
Hallym University, Vietnam
1Department of Chemistry, Hallym University, Korea
|
| Abstract |
Triple-stranded helicates-based metallosupramolecular nanocages are susccessfully synthesized through unique multiple assembly strategy. The prepared discrete molecular nanocages are considered the assembly of six triple-stranded helicates interconnected by four metallic junctions. These are unusual examples of a highly symmetric discrete molecular architectures, resulting from the coordination-driven assembly of in-situ generated modules. The right- and left-handed triple-stranded helicates, structurally analogous to the basic building blocks in molecular nanocages can be synthesized in separated reactions. Owing to the presence of structurally well-defined, highly systematic, and robust cavities of the synthesized cages, the molecular nanocage shows much higher CO2 capture capacity and selectivity compared with the triple-stranded helicates and other single molecules. |
| E-mail |
minhhai061186@gmail.com |
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122nd General Meeting of the KCS